The classification scheme for micaceous minerals is described. According to the size of mineral particles micas are divided into macrocrystalline compounds and microcrystalline clay micas. Macroc rystalline micas are differentiated into (a) Mg-Fe-Al micas, (b) Li-micas, (c) micas with other cations. Vertical boundary in the suggested scheme divides micas into trioctahedral and dioctahedral members. Additional subdivision is carried out on the basis of the extent of Si substitution in tetrahedral positions of their crystal lattice. Microcrystalline (<4μm) micas are subordinate to the crystallochemical scheme for macrocrystalline micas. List of mica species together with their varieties and synonyms is in Table 2., Karel Melka., and Obsahuje bibliografické odkazy
The character of soil cover in anthropogenically affected areas was determined on the basis of soil morphology, particle size distribution, soil chemical properties, soil organic matter properties and mineralogy of clay fraction. The degree of anthropogenic influence was variable in the individual soil profiles. This is probably the first time that data on hot-wate rextractable carbon distribution in soil profile were obtained from the territory of Prague., Anna Žigová, Martin Šťastný, Jana Krejčová and Pavel Hájek., and Obsahuje bibliografické odkazy
Catalytic test reaction of methylbutynol (MBOH) conversion was applied to investigation of natural clays and non-clay minerals from Jordanian (bentonite, kaolinite, diatomite, zeolit e) and Russian (palygorskite, kaolinite, hydromica) deposits as well as H-ZSM-5. Palygorskite and kaolinite containing samples have shown the highest catalytic activity. Conversionove r Jordanian clay minerals decreased in the order: zeolite > bentonite > red kaolinite > white kaolinite > diatomite that agreed to change of acidity, surface area of samples. Sufficient deactivation was observed for H-ZSM-5, kaolinite and hydromica due to adsorption of secondary product in micropores of raw minerals. Products of both acidic and basic pathways of test reaction were formed indicating the presence of acid and basic sites on clays surface, apart from acidic catalyst H-ZSM-5. Theyield ratio of acidic to basic products was above the unity for zeolite, bentonite, red kaolinite, and palygorskite; equal to unity for diatomite and hydromica, and less then unity for white kaolinite. It was observed for kaolinite containing sample that high activation temperature increased conversion of MBOH owing to fo rmation of additional basic sites as a result of mineral dehydroxylation. Rise of montmorillonite content from 30 to 80 % provided 91-97 % of MBOH conversion., Lyudmila Novikova, Larisa Belchinskaya, Frank Roessner and Murad Alsawalha., and Obsahuje bibliografické odkazy
The study was performed in the territory of the Skryje-Týřovice Basin, in the Buchava Formation. The study area falls within the Křivoklátsko Protected Landscape Area. Samples were collected from Albic Luvisol. Parent material was characterized on the basis of thin section study. Soil development was evaluated by parameters such as macromorphological analysis, particle size distribution, pH, base saturation, cation exchange capacity, soil organic matter and mineral composition of clay fraction. Results of the analyses, especially the thickness of Bt horizon and distribution of clay fraction in the soil profile, confirm the process of intensive pedogenetic clay differentiation. Trioctahedral 1:1 regularly interstratified mineral (R=1) containing chlorite and smectite layers (low-charge corrensite) was described for the first time in the soils of the Czech Republic. Corrensite was detected in the Ah horizon of Albic Luvisol under weakly acid reaction conditions in the increasing amount of organic matter using the X-ray diffraction analysis. The distribution of clay minerals in Albic Luvisol showed that soil development is influenced by loess and also volcanic rocks in the lower part of the profile.
The aim of this study was to evaluate an efficiency of clay minerals (kaolinite, illite, Na- and Ca-montmorillonite) in alleviating the water repellency of stearic acid sand during the course of long-term hot and dry spell. This spell was simulated by prolonged drying (incubation) of the samples in oven at 50°C. It was found that the kaolinite addition resulted in a drop in the persistence of water repellency of the stearic acid sand. On the contrary, the Ca-montmorillonite addition increased markedly the persistence of water repellency of the stearic acid sand. In most cases, the illite addition resulted in an increase in the persistence of water repellency, even though not so markedly as it was in the case of Ca-montmorillonite addition. In the case of Na-montmorillonite addition, the striking drop in the persistence of water repellency of the stearic acid sand was registered only after lowering the moisture below 5 %. An increase in the persistence of water repellency of the sand-clay mixture with an increase in the clay amount is another interesting finding, observed in case of kaolinite and Ca-montmorillonite. and Cieľom tejto štúdie bolo zhodnotenie efektívnosti ílových minerálov (kaolinitu, illitu, Na- a Camontmorillonitu) pri znižovaní stálosti vodoodpudivosti piesku pokrytého kyselinou stearovou počas dlhého suchého a teplého obdobia, simulovaného inkubáciou vzoriek pri teplote 50 °C. Zistili sme, že pridanie kaolinitu výrazne znížilo stálosť vodoodpudivosti piesku pokrytého kyselinou stearovou prakticky počas celého cyklu sušenia. Pridanie Ca-montmorillonitu naopak stálosť vodoodpudivosti piesku pokrytého kyselinou stearovou výrazne zvýšilo. Pridanie illitu vo väčšine prípadov zvýšilo stálosť vodoodpudivosti piesku pokrytého kyselinou stearovou, aj keď nie tak výrazne ako pridanie Ca-montmorillonitu. V prípade pridania Na-montmorillonitu sme výrazné zníženie vodoodpudivosti piesku pokrytého kyselinou stearovou zaznamenali až po poklese vlhkosti vzorky pod 5 %. Ďalším zaujímavým poznatkom je vzrast vodoodpudivosti so zvyšujúcim se obsahom ílu, ktorý sme zaregistrovali v prípade kaolinitu a Ca-montmorillonitu.
The evolution of soil cover in the area of Litovel has been determined on the basis of grain-size distribution, mineralogy of clay fraction, chemical and micromorphological analyses. The object of the present study was a chronosequence of soils in Pleistocene sediments. Paleopedological data indicate that the area underwent environmental changes including several cycles of pedogenesis. This area provides evidence of at least two first-order warm periods. The highest degree of polygenesis can be demonstrated by Braunlehm-like Parabraunerde (PK V - Late Holstein Interglacial) and Chernozem which evolved from Haplic Luvisols (PK IV - warm period within the Riss glacial). The upper part of the profile documents different types of pedosediments which indicate erosion processes., Anna Žigová and Martin Šťastný., and Obsahuje bibliografické odkazy
The research has dealt with mineral composition of the dislocation clays developed on the Prague fault. The Prague fault is a tectonic boundary between underlying clayey slates of Záhořany series and Skalka quartzite. The fault zone is filled with clay or sandy-silt to silty-sand matrix with scattered fragments of the surrounding rocks either slates or quart zite. Quartz, illite, kaolinite, chlorite, sporadic feldspar and gypsum were identified in powdered preparations by X-ray diffraction. The clay fraction of the taken samples is composed of illite, less kaolinite and sporadic chlorite and gypsum., Pavel Hájek and Martin Šťastný., and Obsahuje bibliografické odkazy
This study investigates the clay mineralogy of permafrost-affected soils derived from predominantly calcareous loess-like material under the cold ultra-continental climatic conditions of Central Yakutia. These soils are named "Palevye (Pale)" following the Russian Classification, or Cryosols (WRB, 2006). Based on the data obtained, the loess-like substrate of Central Yakutia is enriched by chlorite in comparison with that of the loess-like parent material of European Russia. The clay mineralogy of the fine size fractions (<1μm) of all soil profiles is dominated by a smectitic mineral (most likely random mixed-layer illite-smectite and probably chlorite-smectite where smectite is ≥ 50 %), with subordinate chlorite and illite as well as the products of their transformation with smectite (vermiculite) layers < 50 % in the upper horizons, and finally traces of kaolinite. Pedogenesis has brought about change in the more acidic upper horizons, including a marked reduction in the expandability of the smectitic phase, possibly accounted for by the introduction of non-exchangeable hydroxy-Al into the interlamellar space and / or partial dissolving of smectitic phase, together with a relative reduction in the contents of bothillite and chlorite. Illite has been at least partially transformed to a mixed-layer illite-vermiculite (smectite), whereas chlorite has either been completely decomposed or has transformed to a mixed-layer expandable component. In one profile, the smectitic mineral appears to be absent from the upper horizon, suggesting that it may have been completely decomposed. An alternative explanation is that it has been eluted or translocated down the profile to accumulate in a Bt horizon. The distribution of clay minerals relates to the change of pH values in the profiles (acidic in the upper part, neutral - slightly alkaline in the middle, and alkaline in the basal horizons) possibly determined by seasonal migration of dissolved carbonates., Sofia N. Lessovaia, Sergey V. Goryachkin, Roman V. Desyatkin and Matrena V. Okoneshnikova., and Obsahuje bibliografické odkazy
a1_Phyllosilicates are classified into the following groups: 1 - Neutral 1:1 structures: the kaolinite and serpentine group. 2 - Neutral 2:1 structures: the pyrophyllite and talc group. 3 - High-charge 2:1 structures, non-expansible in polar liquids: illite and the dioctahedral and trioctahedral micas, also brittle micas. 4 - Low- to medium-charge 2:1 structures, expansible phyllosilicates in polar liquids: smectites and vermiculites. 5 - Neutral 2:1:1 structures: chlorites. 6 - Neutral to weak-char ge ribbon structures, so-called pseudophyllosilicates or hormites: palygorskite and sepiolite (fibrous crystalline clay minerals ). 7 - Amorphous clay minerals. Order-disorder states, polymorphism, polytypism, and inters tratifications of phyllosilicates are influenced by several factors: 1) a chemical micromilieu acting during the crystallization in any environment, including the space of clay pseudomorphs after original rock-forming silicates or volcanic glasses; 2) the accepted thermal energy; 3) the permeability. The composition and properties of parent rocks and minerals in the weathering crusts, the elevation, and topography of source areas and climatic conditions control the in tensity of weathering, erosion, and there sulting assemblage of phyllosilicates to be transported after erosion. The enormously high accumulation of phyllosilicates in the sedimentary lithosphere is primarily conditioned by their high up to extremely high chemical stability in water-rich environments (expressed by index of corrosion, IKO). Clastic material eroded fro m weathering crusts and transported in rivers contains overwhelming amounts of phyllosilicates inherited from original rocks. In geological literature, the newly formed phyllosilicates crystallizing in weathering crusts including soils as dominating global source of argillaceous lutite accumulations in the sedimentary lithosphere have been overestimate for a long time., a2_The dissolution of silicates in different dense rocks under conditions of weathering and the crystallization of newly formed phyllosilicates has been strongly and for long periods influenced by chemical microenvironments within each clay pseudomorph. Coarser fragments of eroded argillaceous rocks and crystals of phyllosilicates from different bedrocks and soils are very sensitive to impacts and pressure from fragments of co-transported harder and denser rocks and minerals in turbulent fluvial and similar currents. This is the most important mechanical phenomenon supporting the enormous accumulation of lutite rocks rich in phyllosilicates in the sedimentary lithosphere. The summarized new observations and interpre tations are stressed in eleven key poin ts. Erosion and water transportation of detrital material are explained in the terms of hydration, softening, swelling, physical disintegration, grinding, milling, abrasion, delamination, dispersi on, and sorting. The deposition of phyllosilicates in different fluid dynamics of streams is expressed by Re and Fr numbers and explained as unflocculated and floccu lated suspensions. Phyllosilicates an d accompanying detrital minerals in recent marine muds covering vast areas of seas and oceans as well as in lacustrine muds correspond with those transpor ted in fluvial suspensions., Jiří Konta., and Obsahuje bibliografické odkazy
The prehistory of clay mineralogy is highlighted from the beginnings in ancient Greece to the mineralogical works of Agricola, in particular his famous handbook of mineralogy, entitled De natura fossilium (1546). Starting with a few scattered hints in the works of Archaic and Classic Greek authors, including Aristotle, the first treatment of clays as a part of mineralogy is by Theophrastus. This basic tradition was further supplemented by Roman agricultural writers (Cato, Columella), Hellenistic authors (the ge ographer Strabo and the physicians Diosco rides and Galen), the Roman engineer-architect Vitruvius, and finally summarized in Pliny’s encyclopedia Naturalis historia, which has become the main source for later authors, including Agricola. It is shown to what extent Agricola’s work is just a great summary of this traditional knowledge and to what extent Agricola’s work must be considered as original. In pa rticular, Agricola’s attempt to a rational, combinatorical classification of "earths" is recalled, and aplausible explanation is given for his effort to include additional information on Central European clay depos its and argillaceous raw material occurre nces. However, it is shown that - in contrast to common belief - Agricola was not the first to include "earths" in a mineralogical system. This had been done almost one thousand years earlier by Isidore of Seville., Willi Pabst and Renata Kořánová., and Obsahuje bibliografické odkazy