In presented work, raw, expanded and acid treated vermiculites were used as low-cost and active adsorbents for reducing of environmental pollution with heavy metals. Acid treatment was performed at elevated temperature (95°C) for 2 and 24 h in solution of HNO3. Adsorption capacity towards Fe3+ was studied in column, semi-batch and batch mode. It was shown that all samples are effective in removal of heavy metals; however adsorption mechanism is based not only on ion exchange of interlayer cations but also precipitation/deposition processes. Starting material and modified samples as well as spent adsorbents were characterized with respect to the vermiculite structure using X-ray diffraction method., Agnieszka Węgrzyn, Lucjan Chmielarz, Paweł Zjeżdżalka, Andrzej Kowalczyk, Magdalena Jabłońska, Xavier Baldrich Tolosa and Marek Michalik., and Obsahuje bibliografii
Vermiculite (V) from Brazil with aqueous solutions AgNO3 and/or Cu(NO3)2 was used for preparation of nanocomposites V/Ag, V/Cu, V/AgCu and V/CuAg using two procedures and their effect on bacteria was compared. Structural changes were evaluated using X-ray diffraction (XRD) analysis, Infrared spectroscopy (IRS) and Scanning electron microscopy (SEM). Elemental chemical composition was determined using X-ray fluorescence (XRF) analysis and the solutions were analyzed by Atomic emission spectroscopy with inductively coupled plasma (AES-ICP). Antibacterial properties of Ag- and Cu-vermiculites and combined Ag/Cu-vermiculites were tested on two bacteria groups: (1) Gram-positive, G+, (Staphylococcus aureus and Enterococcus faecalis) and (2) Gram-negative, G-, (Pseudomonas aeruginosa and Klebsiella pneumoniae). The samples under antibacterial testing showed different effective times and minimum inhibitory concentration (MIC) values. The Gram-negative bacteria showed higher sensitivity to the prepared samples than Gram-positive bacteria. The combined Cu/Ag vermiculites stopped the bacterial growth at lower MIC value., Marianna Hundáková, Marta Valášková, Vladimír Tomášek, Erich Pazdziora and Kateřina Matějová., and Obsahuje bibliografii
Vermiculite in its macroscopic form occurs in the Archaean supracrustal rocks exposed towards east of Sargur supracrustal complex in Karnataka state. The present study forms the first detailed work on the occurrence of vermiculite associated with the ultramafic rocks in the Agasthyapura, which lies in the long. 76° 50’ 658” and lat. 12° 15’ 976”. Petrography, X-ray diffraction, FTIR, DTA&TGA, SEM, fluid inclusion and electron probe analyses are presented in this contribution study. The probable origin of vermiculite from biotite through hydrobiotite is discussed., Kikkeri N. Prakash Narasimha, Honnaiah Ramalingaiah, Karel Melka, K. Krishnaveni, Pinnelli S. R. Prasad, Chikkamadaiah Krishnaiah, Katihalli S. Jayappa and Atni V. Ganesha., and Obsahuje bibliografické odkazy
In presented work natural expanded vermiculite was used as a starting material for synthesis of Fe-doped catalysts. Material was modified with increasing amount of Fe by ion-exchange and precipitation of iron oxide. Composite materials were characterized with respect to their structure (X-ray diffraction, Infrared spectra using Diffuse Reflectance), agglomeration state of Fe (Ultraviolet-Visible spectra using Diffuse Reflectance) and chemical composition. Activity in H2O2 decomposition as well as in phenol oxidation was studied in liquid phase at atmospheric pressure and temperature up to 70 °C. It was shown that doping with Fe increases catalytic activity. However, excess of iron resulted in formation of undesired side-products., Agnieszka Węgrzyn, Lucjan Chmielarz, Paweł Zjeżdżalka, Magdalena Jabłońska, Andrzej Kowalczyk, Agata Żelazny, Manuel Vázquez Sulleiro and Marek Michalik., and Obsahuje bibliografii