The known vertical deflection values can be utilised to increase geoid’s accuracy. One of the methods of vertical deflection components (ξ, η) determination is to compare astronomic and geodetic coordinates. Presently it is easy possible to obtain geodetic coordinates with high accuracy from GPS observation. In the article the methods of astronomical CCD observation with aid of two different optical systems are discussed. Project realisation is in preliminary stage and there are no results available yet., Jacek Kudrys., and Obsahuje bibliografické odkazy
An occurrence of tetra-coordinated aluminum in altered coal and low temperature coal ashes was investigated. As altered coal a sample from the Lazy mine (Upper Silesian Coal Basin) was tested, further, low-temperature ashes from different coals were prepared and measured. During preparation the selected coal samples were intensively air-oxidized; 27Al MAS NMR spectra of obtained ashes were then acquired and compared against those for initial coals. A reference wood ash and Al standards were used for identification of Al-forms. It was found that chemical shift at 4 ppm with coals corresponds to that for triaquo-hydroxo-diphenoxido-aluminum(III) complex (THDA), further, the shift at 72 ppm with altered coal and resulting ashes agrees with that for Al tetra-coordinated with oxygen. So, in the presence of coal organics the tetra-coordinated Al is formed under low temperature conditions, because during low temperature ashing the THDA complex is transformed to Al tetra-coordinated with oxygen only at 350 °C. A similar process occurred in the case of oxidation of coal substance under low temperature conditions in the nature at temperatures below 150 °C., Pavel Straka., and Obsahuje bibliografii
The parameters determine waves energy in shallow water zone that pronounces the crucial influence on abrasion of both natural and artificially paved banks. The effort to re-development of the relations was found as absolutely necessary for waves energy calculations. Substantial benefit of the work is found not only in enabling the use of computers while avoiding time-consuming and difficult application of diagrams, but namely in recent recognition that the calculation results showed a risk of underestimate the real impact of wind-induced waves. In some cases, the calculations respecting the above standard produce lower values of waves height and time-period and thus also lower values of wave energy., Tamara Spanilá and Karel Jahoda., and Obsahuje bibliografické odkazy
This paper reports the possibilities of using FTIR spectroscopy and simultaneous thermogravimetry and differential thermal analysis for examination of the structural order of four Czech kaolinite samples (Jimlikov, Sedlec, Olomucany and Unanov deposits) and one kaolinite standard KGa-1b from Georgia deposit obtained from the Source Clays Repository of The Clay Minerals Society (USA). FTIR spectroscopy was used for the classification of the degree of structural order of kaolinite samples by empirical (IR-E) and numerical (IR-N) classification. Differential thermal analysis was used for the determination of the kaolinite disorder degree according to decomposition peak temperature obtained from DTA curves. The resulting trend of decrease in orderliness is: KGA-1b (with the best orderliness) > Jimlikov > Sedlec > Olomucany > Unanov (with the worst orderliness)., Lenka Vaculíková, Eva Plevová, Silvie Vallová and Ivan Koutník., and Obsahuje bibliografii
The character of soil cover in anthropogenically affected areas was determined on the basis of soil morphology, particle size distribution, soil chemical properties, soil organic matter properties and mineralogy of clay fraction. The degree of anthropogenic influence was variable in the individual soil profiles. This is probably the first time that data on hot-wate rextractable carbon distribution in soil profile were obtained from the territory of Prague., Anna Žigová, Martin Šťastný, Jana Krejčová and Pavel Hájek., and Obsahuje bibliografické odkazy
Diatomite is a siliceous sedimentary rock, and it can be used in many industrial applications due to its high porosity, low density porous and permeable structure, chemical resistance, high purity, high specific surface area, absorptive capacity and to its absorbent properties. The best known Portuguese occurrences of diatomite are located in the regions of Óbidos and Rio Maior. The purpose of this research is to characterize the Rio Maior and Amieira diatomite and beneficiate this rock to be used in some potential applications locally or not. The studied diatomites present a fine texture; chemically the samples have a high SiO2 content, the principal minerlas are quartz and amorphous opal. The studied diatomites benefited with temperature and addition of NaCl (acting as accelerator of the crystallization process), with 5 % of NaCl being reduced the transformation temperature of the amorphous opal in opal C / CT at about 200 ºC. The diatomites from Rio Maior and Amieira in natural state has an enormous potential as absorbent, of heavy metals (e.g. in soil contamination) or dyes (textile industry). These diatomites after beneficiation can be used in construction materials (as additive), being more reactive and crystalline than in the natural state, diatomites can be promoters of mechanical resistance in mortars and geopolymers. and Costa Cristiana, Velosa Ana, Cerqueira Angela, Caetano Paulo, Rocha Fernando.
Catalytic test reaction of methylbutynol (MBOH) conversion was applied to investigation of natural clays and non-clay minerals from Jordanian (bentonite, kaolinite, diatomite, zeolit e) and Russian (palygorskite, kaolinite, hydromica) deposits as well as H-ZSM-5. Palygorskite and kaolinite containing samples have shown the highest catalytic activity. Conversionove r Jordanian clay minerals decreased in the order: zeolite > bentonite > red kaolinite > white kaolinite > diatomite that agreed to change of acidity, surface area of samples. Sufficient deactivation was observed for H-ZSM-5, kaolinite and hydromica due to adsorption of secondary product in micropores of raw minerals. Products of both acidic and basic pathways of test reaction were formed indicating the presence of acid and basic sites on clays surface, apart from acidic catalyst H-ZSM-5. Theyield ratio of acidic to basic products was above the unity for zeolite, bentonite, red kaolinite, and palygorskite; equal to unity for diatomite and hydromica, and less then unity for white kaolinite. It was observed for kaolinite containing sample that high activation temperature increased conversion of MBOH owing to fo rmation of additional basic sites as a result of mineral dehydroxylation. Rise of montmorillonite content from 30 to 80 % provided 91-97 % of MBOH conversion., Lyudmila Novikova, Larisa Belchinskaya, Frank Roessner and Murad Alsawalha., and Obsahuje bibliografické odkazy
Magnetotelluric (MT) and audio-magnetotelluric (AMT) methods were applied to clarify the deep geological structure in a coal-mining area in Kushiro, southeastern Hokkaido, Japan. These methods are effective in surveying to deep. Onedimensional inversion was applied to the measurement data obtained in the MT and AMT surveys to estimate the resistivity distributions in the study area. In addition, the one-dimensional inversion method was improved to obtain accurate results by including a smoothing factor and Akaike’s Bayesian information criterion. The inversion method revealed that the lowresistivity zones at depths between 100 and 120 m below sea level correspond with the Yubetsu coal-bearing formation and clay layer, and the thickness of Cretaceous strata was estimated to be more than 4000 m. Finally, the dip of the Osotsunai fault was estimated., Hisafumi Asaue, Misahito Sasahara, Toru Yoshinaga, Yuzo Obara, Kagemi Ushida and Hiroyuki Matsumoto., and Obsahuje bibliografii
The clay deposit of Vila Nova da Rainha (VNR) is included in the lithostratigraphic formation named "Argilas de Tomar", and is located at the lower section of the Tertiary Tagus’ river basin. Clay from one quarry is being extracted for the production of construction ceramics. In this work the firing transformations undergone by VNR clays containing quartz, alkaline feldspar, iron oxy-hydroxides, and clay minerals have been studied. Carbonates have not been identified in these raw materials. The clay layers can be subdivided in three groups based upon composition and ceramic properties. The first group, VNR0, is represented by smectite-kaolinite sandy-silty clay, the second group (VNR1 and VNR2) corresponds to illite-kaolinite bearing clay and the third group (VNR3 and VNR4) is represented by illite-smectite silty clay. The firing process involves the formation of hematite and mullite both influencing the technical properties of the fired products. With regards to the ceramic properties assessed at 1100 ºC the first group showed the lowest total shrinkage value (7.35 %) the highest water absorption value (12.2 %) and the lowest mechanical bending strength value (12.0 MPa); the same properties assessed in the second group provided the highest firing shrinkage values (7.0-5.0 %), the lowest values of water absorption (0.1-0.2 %) and relatively high mechanical bending strength values (47.8-48.0 MPa); the third group showed firing shrinkage values within the range 3.5-4.2 %, water absorption values within the range 1.4-4.5 %, and the highest mechanical bending strength values (49.2-52.0 MPa). The results of the ceramic properties being appraised indicate that the raw materials being studied are suitable for the production of high-quality construction ceramics, such as brick, roof tile and rustic floor tile., João F. Coroado, Eduardo Ferraz, Celso F. Gomes and Fernando Rocha., and Obsahuje bibliografii