The study aimed to determine the linkage between soil exchangeable potassium (K+) concentration and stream water K+ concentration during rainfall and snowmelt events in small catchments with different land use (Carpathian Foothills, Poland). The complementary geochemical and hydrochemical approach used in the study produced new information on the role of particular soil horizons and contributing areas such as hillslope or riparian areas in K+ delivery to stream channels during events. Horizons lying above the nearly impermeable fragipan (Btx) play the most important role in the process of K+ influx to streams during most event types except snowmelts with frozen soils, in all the studied catchments. In the woodland catchment, rapid flushing of K+ from the topsoil Ah horizon with higher hydraulic conductivity (Ksat) and higher exchangeable K+ concentrations than in the lying lower E horizon resulted in a clockwise hysteresis of K+ in stream water during most events. In agricultural catchments, changes in stream water K+ concentration during events were determined by distinct differences between soil exchangeable K+ concentrations on hillslopes and in riparian areas.