Study is focused on the numerical modeling of fly-ash transport in three sands, which was experimentally studied in the laboratory. Sands were packed in glass cylinders with diameter of 5.52 cm and height of 18 cm. Sands were also packed in plastic cylinders with diameter of 30 cm and height of 40 cm. The fly-ash and pulse infiltrations were applied on the top of all cylinders. Visually observed and gravimetrically evaluated fly-ash migration in small cylinders corresponded to fly-ash mobility in large columns detected using the SM400 Kappameter. The HYDRUS-1D code was used to simulate observed fly-ash transport. Parameters of soil hydraulic functions were either obtained using the Tempe cells and the RETC program or estimated using numerical inversion of transient water flow data measured in both types of columns using HYDRUS-1D. Parameters characterizing colloid transport in sands were then estimated from the final fly-ash distribution in sandy columns using attachment/detachment concept in HYDRUS-1D. Fly-ash mobility increased with increasing sand particle sizes, e.g. pore sizes. Particle sizes and pore water velocity influenced the attachment coefficient, which was calculated assuming filtration theory. The same longitudinal dispersivity, sticking efficiency and detachment coefficient sufficiently characterized fly-ash behavior in all sands. and Studie je zaměřena na numerické modelování transportu úletového popílku ve třech píscích, který byl experimentálně studován v laboratoři. Písky byly nahutněny ve skleněných válcích o průměru 5,52 cm a výšce 18 cm. Písky byly také nahutněny v plastových válcích o průměru 30 cm a výšce 40 cm. Na povrchu válců byly aplikovány jednorázové infiltrace vody s popílkem. Migrace úletového popílku pozorovaná vizuálně a zjištěná gravimetricky v malých válcích odpovídala mobilitě úletového popílku detekované Kappametrem SM400 ve velkých válcích. Pozorovaný transport úletového popílku byl simulován programem HYDRUS-1D. Parametry hydraulických funkcí byly získány buď pomocí Tempských cel a programu RETC nebo odhadovány numerickou inverzí transientních data měřených na obou typech válců programem HYDRUS-1D. Parametry charakterizující transport koloidů v píscích byly potom odhadovány z konečné distribuce úletového popílku v písčitých sloupcích užitím konceptu attachment/detachment (připojení/odpojení) v programu HYDRUS-1D. Mobilita úletového popílku se zvyšovala se zvyšující se velikostí písčitých zrn, tj. s velikostí pórů. Velikost zrn a pórová rychlost ovlivnila depoziční (attachment) koeficient, který byl počítán na základě filtrační teorie. Stejné hodnoty podélné disperze, efektivity blokování (sticking efficiency) a mobilizačního (detachement) koeficientu charakterizovaly chování úletového popílku ve všech píscích.
Treated water from wastewater treatment plants that is increasingly used for irrigation may contain pharmaceuticals and, thus, contaminate soils. Therefore, this study focused on the impact of soil conditions on the root uptake of selected pharmaceuticals and their transformation in a chosen soil–plant system. Green pea plants were planted in 3 soils. Plants were initially irrigated with tap water. Next, they were irrigated for 20 days with a solution of either atenolol (ATE), sulfamethoxazole (SUL), carbamazepine (CAR), or all of these three compounds. The concentrations of pharmaceuticals and their metabolites [atenolol acid (AAC), N1-acetyl sulfamethoxazole (N1AS), N4-acetyl sulfamethoxazole (N4AS), carbamazepine 10,11-epoxide (EPC), 10,11-dihydrocarbamazepine (DHC), trans-10,11- dihydro-10,11-dihydroxy carbamazepine (RTC), and oxcarbazepine (OXC)] in soils and plant tissues were evaluated after harvest. The study confirmed high (CAR), moderate (ATE, AAC, SUL), and minor (N4AC) root uptake of the studied compounds by the green pea plants, nonrestricted transfer of the CAR species into the different plant tissues, and a very high efficiency in metabolizing CAR in the stems and leaves. The results showed neither a synergic nor competitive influence of the application of all compounds in the solution on their uptake by plants. The statistical analysis proved the negative relationships between the CAR sorption coefficients and the concentrations of CAR, EPC, and OXC in the roots (R = –0.916, –0.932, and –0.925, respectively) and stems (R = –0.837, –0.844, and –0.847, respectively).